Symmetry-broken crystal growth via diffusion-limited solidification
Dendrites form when surface tension anisotropy breaks the circular Mullins-Sekerka symmetry. The phase-field model with anisotropic surface energy:
The n-fold anisotropy selects specific tip orientations. Solvability theory (Ivantsov 1947, corrected): the selected tip velocity V* and radius ρ* satisfy σ* = 2Dα/V*ρ*² = fixed constant dependent on anisotropy. Higher ε → faster tips, thinner stalks, richer sidebranching.