Lyapunov's direct method (1892): if you can find a positive-definite function V whose time derivative is non-positive along all trajectories, the equilibrium is stable. No need to solve the ODE.
Region of attraction: the set {x: V(x) ≤ c, V̇(x) ≤ 0} is an invariant sublevel set — any trajectory starting inside stays inside. This provides a certificate for the basin of attraction.
For Van der Pol, the quadratic V is not a perfect Lyapunov function — V̇ changes sign, reflecting the limit cycle. The system is not globally stable to zero.