Ecological Stoichiometry
Redfield Ratio C:N:P = 106:16:1 · Droop Model · Nutrient Cycling
C:P ratio
106
Redfield: 106
C:N ratio
6.6
Redfield: 6.6
Limiting nutrient
N
Liebig's Law
Redfield's discovery (1934): Ocean phytoplankton maintain a near-constant
elemental ratio of C:N:P = 106:16:1 (by atoms). This matches deep ocean dissolved nutrients —
implying life sets ocean chemistry over geological timescales.
The Droop model captures luxury uptake: growth rate μ = μmax(1 − Qmin/Q)
where Q is internal quota. Liebig's Law of the Minimum: only the most limiting
nutrient controls growth. N-limitation → excess P released; P-limitation → N accumulates in water.