Unique (unitary) hues — the four colors that appear "pure," containing no trace of another hue.
Unique Red (~700 nm or ~450 nm): no yellow, no blue tinge.
Unique Green (~530–540 nm): no red, no blue.
Unique Yellow (~580 nm): no red, no green — exactly where L−M=0.
Unique Blue (~470 nm): no red, no green.
These four hues are linguistically universal (Berlin & Kay 1969): every language with 4+ color terms has words for them. Opponent theory predicts exactly these zero-crossings.