Colloidal Gel — Arrested Phase Separation

Short-range attraction + repulsion arrests spinodal decomposition into fractal network

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Colloidal gels form when short-range attractions cause spinodal decomposition but glass transition arrests the dense phase before it can fully coarsen. The result is a space-spanning fractal network (d_f ≈ 2.0–2.5) that supports stress. ε/kT > 3 and low φ are typical gel conditions.